Unexplored nucleophilic ring opening of aziridines.
نویسندگان
چکیده
The reactivity of dianions of carboxylic acids towards aziridines has been studied. Although, a similar reactivity to that of enolates from ketones, esters or amides has been observed, the method directly yields γ-aminoacids in one step. The method is complementary of previous results of enenediolate reactivity with other electrophiles. A comparative study with the reactivity of this enediolates with epoxides is included.
منابع مشابه
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ورودعنوان ژورنال:
- Molecules
دوره 15 12 شماره
صفحات -
تاریخ انتشار 2010